Copper-catalyzed radical-mediated intermolecular cyanomonofluoroalkylation of alkenes and alkynes.

A novel copper-catalyzed three-component reaction of monofluoroalkylation agents, alkenes and TMSCN is described. In addition, alkynes could also be compatible with the reaction system to obtain three-component products for the first time with moderate yield and excellent E/Z stereoselectivity. This reaction provides a facile method for the synthesis of cyanomonofluoroalkyl compounds, which may serve as potentially useful organic intermediates for further transformations. Preliminary mechanistic investigation indicated that monofluoroalkyl free radicals were involved in the cyanomonofluoroalkylation process.

The facile synthesis of a single atom-dispersed silver-modified ultrathin g-C3N4 hybrid for the enhanced visible-light photocatalytic degradation of sulfamethazine with peroxymonosulfate.

Enabling the optimal usage of solar energy is considered to be one of the most pressing challenges in the photocatalytic remediation of water resident contaminants. Herein, a single-atom dispersed Ag loaded ultrathin g-C3N4 hybrid (AgTCM/UCN) was prepared through a facile co-polymerization of dicyandiamide with silver tricyanomethanide (AgTCM) and NH4Cl, and used as a visible light driven photocatalyst for the degradation of sulfamethazine (SMT) in the presence of peroxymonosulfate (PMS). Under UV light, visible light and simulated sunlight irradiation, the AgTCM/UCN/PMS process showed higher efficiency for SMT degradation than AgTCM/UCN, UCN/PMS, and g-C3N4/PMS systems. This enhanced photocatalytic activity may be attributed to the synergistic effects encompassing the surface plasmon resonance (SPR) of Ag, high surface area of UCN, and efficient charge separation of PMS. Electron-spin resonance (ESR) and reactive species (RSs) scavenger-quenching experiments revealed that SO4˙- was generated following the addition of PMS, whereas O2˙- and h+ were predominantly responsible for the degradation of SMT. Three degradation pathways of SMT were deduced, including the cleavage of sulfonamide bonds, SO2 extrusion, and the oxidation of the aniline moiety, based on mass spectrometry and theoretical calculations. The degradation of SMT in ambient water revealed that the AgTCM/UCN/PMS photocatalytic process can be efficaciously applied for the remediation of SMT contaminated natural waters, particularly sea water.